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Yeah, I have to say, a top five is not good enough to include all the good songs. Although, at the same time, I'm lazy, so I'm only going to do a top fifty, even though there are many other songs out there that could be on here.

50- Dark Whisper- Disgaea
49- Deeper into the Code- DooM
48- Boss Battle- Mystic Quest
47- Fever- Dr. Mario
46- Kokori Forest- LoZ: OoT
45- Underground- SMB
44- Skedar Mystery- Perfect Dark
43- Opening- Xenosaga
42- Red Moon- Disgaea
41- Dis- DooM
40- Dark Combat- Perfect Dark
39- Castle Tank Boss- Timesplitters: Future Perfect
38- Hazy Maze Cave- Mario 64
37- Sorrowful Angel- Disgaea
36- Pogo- RF
35- Castle Theme- SMW
34- Divine Spirit of Language- Star Ocean: Till The End Of Time
33- At Doom's Gate- DooM
32- Heavy 4- RF 2
31- Mojo Mansion- Maui Mallard in: Cold Shadow
30- Malevolent Souls- Castlevania: Lament of Innocence
29- Music B- Tetris
28- Frog's Theme- Chrono Trigger
27- Infern Isle- DQM: Joker
26- Champion Theme: Pokemon: LG/FR
25- Intro song- Bleach: Dark Souls
24- Interval of Freezed Time- Star Ocean: Till the End of Time
23- Prologue- Xenosaga
22- Broken Promise- Dark Cloud
21- The Imp's Song- DooM
20- Lavender Town: Pokemon RBY
19- Sandy's City- DooM II
18- Royal Valley- LoZ: Minish Cap
17- Kokoro- Xenosaga
16- Strains of Insanity- Chrono Trigger
15- The Realm of the Dead- Maui Mallard in: Cold Shadow
14- Midna's Desperation- LoZ: Twilight Princess
13- The Edge of Decision- Tales of the Abyss
12- "Mt. Erebus"- PSX DooM
11- Serenade of Water- Legend of Zelda: Ocarina of Time
10- Champion Battle- Pokemon: GSC
9- In the Sky- Grandia III
8- Bitter Dance- Star Ocean: Till the End of Time
7- Song of Storms- Legend of Zelda: Ocarina of Time
6- Showdown With Magus- Chrono Trigger
5- Manison of Madness- TimeSplitters: Future Perfect
4- Great Assize- Grandia III
3- Pain- Xenosaga
2- Finish the Promise- Tales of the Abyss
1- A Little Bird Who Forgot How to Fly- Star Ocean: Till the End Of Time

Most of these, especially either end of the list, I know are right, but the middle may not be set up perfectly. It's late here, and I'm trying to finish so I can get a decent nigt's sleep for once. But for the most part, it's correct.